6533b855fe1ef96bd12b04f5
RESEARCH PRODUCT
Unexpected photochemistry and charge-transfer complexes of [CB11H12]2 carborane
Francesc X. Llabrés Y XamenaLaura TeruelM.sales Galletero PedrocheAvelino CormaHermenegildo Garcíasubject
Photochemistry ; Carborane ; Laser ExcitationPhotochemistryLaser ExcitationUNESCO::QUÍMICAUNESCO::QUÍMICA::Química analítica:QUÍMICA::Química analítica [UNESCO]:QUÍMICA [UNESCO]Carboranedescription
Although the [CB11H12]¯carborane does not exhibit an absorption band inUV, its triplet excited state can be generated upon 308 nm laser excitation; also unexpectedly carborane acts as electron donor forming a charge transfer complex with methylviologen that upon illumination gives rise to viologen radical cation. Galletero Pedroche, M.Sales, Sales.Galletero@uv.es
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-01-01 |