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RESEARCH PRODUCT

Electrochemical Interfaces: At the Border Line

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The sections in this article are Introduction Basic Concepts Thermodynamics of Electrified Interfaces Classical Models of Electrified Interfaces Helmholtz Model Gouy–Chapman–Stern–Grahame Model Diffuse and Compact Layer Properties Grahame Model in Comparison with Capacitance Data for Liquid Electrodes Compact Layer Properties Manifestations of the Diffuse Layer in Kinetics of Electrode Reactions Electrokinetic Phenomena Solid Electrodes: Effects of Polycrystallinity and Surface Roughness “Uniform” Model of Solid Electrodes. Surface Roughness Crystallographic Inhomogeneity Effects for Solid Electrode Surfaces EDL Structure for NonUniform Electrode Surfaces Surface Roughness Effect on the Diffuse-Layer Capacitance Semi-phenomenological Nonlocal Theory of the Double Layer Basic Equations “Dipolar” Models of the Compact Layer Two-State Model Multistate Models The Role of Metal Electrons Surface Electronic Profile and its Response to Charging Response to Charging of the Electrochemical Interface and the Compact-Layer Capacitance: Main Qualitative Effects Optical Response and the Interfacial Structure Effects of the Molecular Nature of Electrolyte Solutions Ionic Adsorption Qualitative Aspects Ion Adsorption Models Image Potential for Ions in the Diffuse or Compact Layer Interaction Between Adsorbed Ions Statistical Mechanics of Adsorbed Ion Ensemble Ion Adsorption Isotherm Electric Field-Induced Modifications of the Surface Structure Electrochemical Missing Row Reconstruction: Facts and Speculations Driving Force for Reconstruction Ising Model. Order–Disorder Transitions Roughening Transitions Soft Electrochemical Interfaces Capillary Waves at ITIES. Field Effect on Capillary Waves and Capillary Waves Effect on Capacitance Ion Penetration into an “Unfriendly Medium” From Basic Concepts to Surface Electrochemistry