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RESEARCH PRODUCT
Über eine Reaktion vono-Hydroxybenzylalkoholen mit Estern von Säuren des Phosphors mit der Koordinationszahl 3
Walter Vogtsubject
chemistry.chemical_classificationchemistry.chemical_compoundchemistryTrimethyl phosphiteOrganic chemistryAlcoholRing (chemistry)Medicinal chemistryDimethyl esterAlkylPhosphinedescription
Abstract o-Hydroxybenzyl alcohol reacts with trimethyl phosphite under smooth conditions to o-hydroxyphenylmethane phosphonic acid dimethyl ester. This unusual reaction is of widest applicability. Derivatives of o-hydroxybenzyl alcohol independent of type, number or position of substituents in the ring, react with alkyl esters of phosphorous, phosphonous or phosphinous acids in an analogous process, forming the corresponding o-hydroxyphenylmethane phosphonic or phosphinic esters or phosphine oxides.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1978-09-01 | Phosphorus and Sulfur and the Related Elements |