6533b855fe1ef96bd12b1b8c

RESEARCH PRODUCT

Studies on antimony trifluoride in thiocyanate salt matrices. Evidence for the formation of fluoro-thiocyanato anti-mony(III) species

N. BertazziG. Alonzo

subject

Antimony trifluoridechemistry.chemical_classificationThiocyanateInfraredOrganic ChemistryInorganic chemistrychemistry.chemical_elementSalt (chemistry)Antimony compoundsBiochemistryInorganic Chemistrychemistry.chemical_compoundchemistryAntimonyMössbauer spectroscopyMelting pointEnvironmental ChemistryPhysical and Theoretical Chemistry

description

Abstract Antimony trifluoride can be dissolved in fused KNCS or NH4NCS giving yellow-orange solutions which are stable only for a short time just above their melting point. Infrared an Mossbauer results on solidified samples reveal the formation of mixed fluoro-thiocyanato antimony(III) species and indicate a different behaviour in the two matrices.

https://doi.org/10.1016/s0022-1139(00)81562-6