6533b856fe1ef96bd12b1e69
RESEARCH PRODUCT
Cu(I) complexes with diethoxyphosphoryl-1,10-phenanthrolines in catalysis of C–C and C–heteroatom bonds formation
Alla Bessmertnykh-lemeuneIrina P. BeletskayaA. Yu. MitrofanovA. Yu. Mitrofanovsubject
Substitution reactionAddition reaction010405 organic chemistryHeteroatomchemistry.chemical_element010402 general chemistry01 natural sciencesMedicinal chemistryCopper0104 chemical sciences3. Good healthCatalysisInorganic Chemistrychemistry.chemical_compoundPhenylacetylenechemistryMaterials ChemistryOrganic chemistry[CHIM]Chemical SciencesPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUSdescription
Abstract Diethoxyphosphoryl substituted 1,10-phenanthroline copper(I) complexes were tested as catalysts in the Sonogashira-type reaction, α-arylation of phosphoryl-stabilized C–H acids, C–N, C–P bond forming reactions (substitution reactions) and in the reaction of phenylacetylene and bis(pinacolato)diboron (addition reaction). The complexes demonstrate fairly high catalytic activity and in some cases their efficiency is superior to that of the parent Cu(phen)(PPh 3 )Br (phen = phenanthroline).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-05-01 |