6533b856fe1ef96bd12b276e

RESEARCH PRODUCT

The Cation as a Tool to Get Spin-Canted Three-Dimensional Iron(III) Networks

Giovanni De MunnoFrancesc LloretDonatella ArmentanoDavide M. ProserpioTeresa F. MastropietroMiguel Julve

subject

Inorganic ChemistryCrystallographychemistry.chemical_compoundchemistryMineralogyAmmoniumPhysical and Theoretical ChemistrySpin (physics)

description

Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T(c) values ranging from 40 to 56 K. The value of T(c) varies with the cation despite the lack of significant structural modifications.

https://doi.org/10.1021/ic049345z