6533b856fe1ef96bd12b2a22

RESEARCH PRODUCT

Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages

Niklas StruchFilip TopicKari RissanenArne Lützen

subject

electron-deficient trifluoromethyl-substituted sub-components

description

Two supramolecular tetrahedral cages based on a new electron-deficient trifluoromethyl-substituted pyridylimine ligand are synthesised by sub-component self-assembly. Their structures are characterised by NMR und UV-Vis spectroscopy, high-resolution mass spectrometry and single crystal X-ray diffraction. The iron(II) complex shows host–guest chemistry, complex-to-complex transformations and novel electronic properties. peerReviewed

http://urn.fi/URN:NBN:fi:jyu-201708303617