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RESEARCH PRODUCT

New Sesquiterpene Lactones and Other Constituents fromCentaurea paui

Begoña GarcíaLuz CardonaJosé R. PedroM. Carmen MuñozFrancisca I. Navarro

subject

chemistry.chemical_compoundPhytochemistryChemistryStereochemistryCentaurea pauiOrganic ChemistryOrganic chemistryGeneral ChemistryNuclear magnetic resonance spectroscopyPhysical and Theoretical ChemistrySesquiterpeneDerivative (chemistry)Terpenoid

description

Aerial parts of Centaurea paui afforded, in addition to several known sesquiterpene lactones, the two new elemanolides 2–4, the new elemane derivative 5 as well as the five new heliangolides 14–18. Their structures were elucidated by spectroscopic methods, especially high-field NMR spectroscopy. The structure of the heliangolide 12 previously isolated from this plant, has been confirmed by X-ray diffraction.

https://doi.org/10.1002/jlac.199719970313