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RESEARCH PRODUCT

Synthesis and characterization of optically active 2,4-disubstituted-2-oxazolines and their polymerization

Rolf C. SchulzXin Qui Guo

subject

Polymers and PlasticsChemistryOrganic Chemistrytechnology industry and agricultureCationic polymerizationmacromolecular substancesOptically activeRing-opening polymerizationCharacterization (materials science)chemistry.chemical_compoundPolymerizationPolymer chemistryMaterials ChemistryOrganic chemistryMethyl trifluoromethanesulfonate

description

Four different optically active 2,4-disubstituted-2-oxazolines were synthesized and characterized. Cationic polymerization of these oxazolines were studied. Three of the oxazolines could be polymerized using methyl trifluoromethanesulfonate as initiator. S-(–)-2-Phenyl-4-isopropyl-2-oxazoline could not be polymerized under the conditions used.

https://doi.org/10.1002/pi.1994.210340216