ChemInform Abstract: Catalytic Aminomercuration of Olefins in a Tandem Aminomercuration-Deoxymercuration; One-Step Synthesis of Secondary N-Arylallylamines from Allylalcohols.

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RESEARCH PRODUCT

ChemInform Abstract: Catalytic Aminomercuration of Olefins in a Tandem Aminomercuration-Deoxymercuration; One-Step Synthesis of Secondary N-Arylallylamines from Allylalcohols.

José Barluenga Gregorio Asensio Julia Pérez-prieto

subject

chemistry.chemical_compound Primary (chemistry)Tetrafluoroborate chemistry Tandem chemistry.chemical_element One-Step General Medicine Combinatorial chemistry Stoichiometry Mercury (element)Catalysis

description

Abstract Allyl alcohols react with primary aromatic amines and stoichiometric amounts of mercury(II) tetrafluoroborate to give mixtures of mono- and diallyl anilines. However, the use of the tandem aminomercuration-deoxymercuration promoted by catalytic mercury(II) tetrafluoroborate allows to perform regiospecifically the monoallylation reaction with very high yields. A mechanism is proposed to account for the observed results.

year	journal	country	edition	language
1990-08-07	ChemInform

https://doi.org/10.1002/chin.199032087

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