ChemInform Abstract: Heterocyclic Photorearrangements. Photoinduced Rearrangement of 3-Styryl-1,2,4-oxadiazoles.

6533b856fe1ef96bd12b2f62

RESEARCH PRODUCT

ChemInform Abstract: Heterocyclic Photorearrangements. Photoinduced Rearrangement of 3-Styryl-1,2,4-oxadiazoles.

Giuseppe Cusmano Silvestre Buscemi Michelangelo Gruttadauria

subject

chemistry.chemical_compound Chemistry Photodissociation Quinoline Closure (topology)Moiety General Medicine Methanol Ring (chemistry)Medicinal chemistry

description

The photochemical behaviour of 3-styryl-5-phenyl-(5-methyl)-1,2,4-oxadiazoles in methanol at 254 nm has been investigated. A photoinduced rearrangement to the quinoline system has been pointed out and explained as proceeding through an initial photolysis of the ring ON bond, followed by a six membered ring closure reaction involving the styryl moiety.

year	journal	country	edition	language
1990-12-04	ChemInform

https://doi.org/10.1002/chin.199049099

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