6533b856fe1ef96bd12b3025
RESEARCH PRODUCT
EPR, ENDOR and TRIPLE resonance of amino-substituted 9,10-anthraquinone radicals and the rotation of the amino groups in the solution phase
Jussi ElorantaHilkka HeikkiläReijo MäkeläMikko VuolleVirpi VatanenAntti Grönroossubject
RadicalResonanceGeneral ChemistryENDORRotationAnthraquinoneSolution phaselaw.inventionchemistry.chemical_compoundAminoanthraquinoneschemistryRotation barrierTRIPLEComputational chemistrylawPhysical chemistryGeneral Materials ScienceEPRElectron paramagnetic resonancedescription
EPR, ENDOR and TRIPLE resonance spectra were recorded for 1-amino-9,10-anthraquinone (1-aminoAQ), 2-aminoAQ, 1,2-diaminoAQ, 1.4-diaminoAQ, 1,5-diaminoAQ and 2,6-diaminoAQ anion radicals in the solution phase. The rotation of the amino groups is discussed with reference to the experimental data. Rotation barrier calculations were carried out using B3PW91/3-21G* density functional method. The amino groups at positions 1, 4, 5, 8 were found not to be in rotational movement up to the EPR time-scale.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1996-11-01 | Magnetic Resonance in Chemistry |