6533b857fe1ef96bd12b38a1

RESEARCH PRODUCT

Chiral/Achiral Copolymers of Biphenylylacetylenes Bearing Various Substituents: Chiral Amplification through Copolymerization, Followed by Enhancement/Inversion and Memory of the Macromolecular Helicity

Tomoyuki IkaiEiji YashimaKazuya InoueKatsuhiro MaedaRyoma IshidateKübra KaygisizKübra Kaygisiz

subject

Bearing (mechanical)Materials sciencePolymers and PlasticsOrganic Chemistry02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesHelicityInversion (discrete mathematics)0104 chemical scienceslaw.inventionInorganic ChemistryCrystallographylawMaterials ChemistryCopolymer0210 nano-technologyMacromolecule

description

A series of dynamic helical homo- and copolymers of chiral and/or achiral biphenylylacetylenes (PBPAs) bearing achiral methoxymethoxy or acetyloxy groups at the 2,2′-positions along with a chiral o...

https://doi.org/10.1021/acs.macromol.9b02727