6533b857fe1ef96bd12b3f8c

RESEARCH PRODUCT

Novel platinum(II) complexes with heterociclyc ligands: Synthesis and structural chracterization.

Simona RubinoMaria Assunta GirasoloGiancarlo Stocco

subject

mononuclear platinum complexes heterocyclic ligands

description

An array of mononuclear complexes of Pt(II) with triazine and (benzimidazolyl)pyridine heterocycles is reported. The mononuclear complexes [PtCl2(Kdptdn)] [dbtdn=5,6- diphenyl-3-(2-pyridyl)-1,2,4-triazine-4’,4’’-disulfonate sodium salt hydrate], [PtCl2(bbp)] [bbp=2,6-bis(2-benzimidazolyl)pyridine] and [PtCl2(H2dpt)]PtCl4 [dpt=5,6-diphenyl-3-(2- pyridyl)-1,2,4-triazine] have been prepared and structurally characterized. Both neutral and ionic complexes are present, with bifunctional Pt(II) moieties, whose size and shape enable them to behave as novel scaffolds for DNA binding.

http://hdl.handle.net/10447/44171