Towards a Library of “Early‐Late” Ti–Ru Bimetallic Complexes

6533b857fe1ef96bd12b436d

RESEARCH PRODUCT

Towards a Library of “Early‐Late” Ti–Ru Bimetallic Complexes

Philippe Richard Pierre Le Gendre Claude Moïse Laurianne Bareille

subject

Ligand Stereochemistry Difluoride chemistry.chemical_element Crystal structure Medicinal chemistry Chloride Ruthenium Inorganic Chemistry chemistry.chemical_compound chemistry Sodium benzoate medicine Bimetallic strip Titanium medicine.drug

description

A series of new titanocene phosphanes 3–6 have been prepared by replacing both chloride atoms at the titanium atom of the complexes [TiCl2(η5-C5H5){η5-C5H4(CH2)2PR2}] (1: R = Ph; 2: R = Cy) by sodium fluoride or sodium benzoate in two-phase systems. Treatment of these new metalloligands with the binuclear complex [(p-cymene)RuCl2]2 affords the targeted titanocene difluoride and titanocene dibenzoate bimetallic ruthenium complexes 8–11. The first chiral Ti–Ru bimetallic complex 12 bearing a binaphthyloxy ligand at the titanium centre has been synthesised in this way. In each series, an X-ray crystal structure has been determined. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

year	journal	country	edition	language
2005-06-01	European Journal of Inorganic Chemistry

https://doi.org/10.1002/ejic.200401028

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