6533b857fe1ef96bd12b4cb9

RESEARCH PRODUCT

Polycondensed nitrogen heterocycles. Part19. Pyrrolo[1,2-f]phenanthridines by pschorr-type cyclization brought about by hypophosphorous acid

Girolamo CirrincioneIsabella D'asdiaGaetano DattoloEnrico AielloAnna Maria Almerico

subject

chemistry.chemical_compoundAcetic acidHypophosphorous acidchemistryOrganic ChemistryOrganic chemistrychemistry.chemical_elementNuclear magnetic resonance spectroscopyNitrogen

description

Pyrrolo[1,2-f]phenanthridines were prepared in good yields by the diazotization in acetic acid of the amines la,b and subsequent treatment with hypophosphorous acid. The necessity for hypophosphorous acid in the reaction was demonstrated.

https://doi.org/10.1002/jhet.5570230522