6533b857fe1ef96bd12b4d39
RESEARCH PRODUCT
Finite perturbation calculations for the static dipole polarizabilities of the first-row atoms
Wilfried MeyerHans-joachim Wernersubject
PhysicsDipoleNeonchemistryPhysics::Atomic and Molecular ClustersPerturbation (astronomy)chemistry.chemical_elementPhysics::Atomic PhysicsAtomic physicsWave functionMolecular physicsdescription
Static dipole polarizabilities are calculated from self-consistent-field and highly correlated wave functions for the ground states of the atoms Li through Ne. The correlation contributions to the polarizabilities are found to vary between -16% for Be and + 14% for F. The polarizabilities as obtained from the coupled-electron-pair approximation are expected to be accurate to about 2%.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1976-01-01 | Physical Review A |