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RESEARCH PRODUCT

ChemInform Abstract: Recyclable Heterogeneous Palladium Catalysts in Pure Water: Sustainable Developments in Suzuki, Heck, Sonogashira and Tsuji-Trost Reactions

Luma Nassar-hardyJean-cyrille HiersoEric FouquetFrançois-xavier FelpinMarc Lamblin

subject

Green chemistryChemistrySonogashira couplingOrganic chemistrychemistry.chemical_elementGeneral MedicineBond formationHeterogeneous catalysisPalladiumReusabilityCatalysis

description

This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium-catalyzed transformations for carbon-carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji-Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.

https://doi.org/10.1002/chin.201020212