6533b857fe1ef96bd12b4e1b

RESEARCH PRODUCT

Hf27Si6P10, a novel metal-rich compound with P2 groups

Chang-cang HuangWolfgang TremelJoerg Neuhausen

subject

ChemistryStereochemistryMetals and AlloysGeneral ChemistryStructure typeCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsReduction (complexity)MetalCrystallographyFeature (computer vision)visual_artMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumElectronic band structureTernary operation

description

The new ternary metal rich compound Hf27Si6P10 has been synthesized by reduction of HfP with Hf and Si; Hf27Si6P10 crystallizes in a new structure type, a characteristic and unexpected feature of which is the presence of P2 groups; the structural results are interpreted with the aid of high-level band structure calculations.

https://doi.org/10.1039/a906873b