Highlights of metal ion-based photochemical switches

6533b858fe1ef96bd12b578a

RESEARCH PRODUCT

Highlights of metal ion-based photochemical switches

Claudia Giorgi Fernando Pina Enrique García-españa Antonio Bianchi Estefanía Delgado‐pinar

subject

Photoisomerization Chemistry Photochemistry Inorganic Chemistry Metal chemistry.chemical_compound Chemical species Azobenzene Diarylethene visual_art Materials Chemistry visual_art.visual_art_medium Light emission Physical and Theoretical Chemistry

description

Abstract Selected metal complexes behaving as photochemical switches, mostly operating by light emission/absorption without the intervention of any added chemical species, are reviewed. First, the switching mechanisms are analyzed to offer readers an easier understanding of the described systems. Examples of photochemical switching based on complexation/decomplexation processes and photo-bistable systems, comprising metal complexes with azobenzene, azopyridine, diarylethene, spirocyclic and rhodamine ligands, make the central body of the review. These examples were chosen to provide an overview of the evolution of metal-ion based photochemical switches, collecting together historical cases and more recent systems mainly reported in the last 15 years.

year	journal	country	edition	language
2014-02-01	Coordination Chemistry Reviews

https://doi.org/10.1016/j.ccr.2013.09.023

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