6533b858fe1ef96bd12b59d7
RESEARCH PRODUCT
Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks
Mario Palacios-corellaC. Sánchez-sánchezJuan M. Clemente-juanMiguel Clemente-leónEugenio CoronadoVíctor García-lópezsubject
Materials science010405 organic chemistryLigandRelaxation (NMR)Química organometàl·lica010402 general chemistry01 natural sciencesOxalate3. Good health0104 chemical scienceslaw.inventionInorganic Chemistrychemistry.chemical_compoundMagnetizationCrystallographyOctahedronchemistryFerromagnetismlawElectron paramagnetic resonanceBimetallic stripdescription
The 1 : 2 and 1 : 1 Co(ii) complexes of the L ligand (L = 6-(3,5-diamino-2,4,6-triazinyl)2,2'-bipyridine) with formulas [CoII(L)2](ClO4)2·0.5MeCN·Et2O (1) and [CoII(L)(CH3CN)2(H2O)](ClO4)2·MeCN (2) have been prepared. The structural and magnetic characterization of the two compounds shows that they contain octahedral high-spin Co(ii) and present a field-induced slow relaxation of the magnetization. 1 has been inserted into a bimetallic oxalate-based network leading to a novel achiral 3D compound of formula [CoII(L)2][MnIICrIII(ox)3]2·(solvate) (3) exhibiting ferromagnetic ordering below 4.6 K. EPR measurements suggest a weak magnetic coupling between the two sublattices.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-05-05 |