6533b858fe1ef96bd12b5b95
RESEARCH PRODUCT
A PERVAPORATION PHOTOCATALYTIC REACTOR FOR THE GREEN SYNTHESIS OF VANILLIN
Vincenzo AugugliaroVittorio LoddoLeonardo PalmisanoGiovanni PalmisanoA.g. CardilloG. Camera-rodasubject
General Chemical EngineeringTiO2 photocatalysis pervaporation green synthesisMembrane reactorIndustrial and Manufacturing EngineeringMembrane technologyReaction ratechemistry.chemical_compoundPhotocatalysiEnvironmental ChemistryOrganic chemistryVANILLINMembrane reactorChemistryIntegrated proceVanillinINTEGRATED PROCESSPROCESS INTENSIFICATIONGeneral ChemistryMembranePhotocatalysis Pervaporation Membrane reactor Integrated process Green chemistry VanillinChemical engineeringGreen chemistryPERVAPORATIONYield (chemistry)PhotocatalysisPervaporationPHOTOCATALYSISdescription
Abstract Pervaporation is the ideal membrane separation process to be coupled with photocatalysis for the green synthesis of vanillin from ferulic acid. In fact the operative conditions of the two processes are absolutely congruent and the integration is straightforward even operating with separate equipments. The utilization of a highly selective membrane allows the continuous recovery of vanillin by pervaporation from the reacting solution, so that its oxidative degradation is largely avoided and the yield is substantially enhanced. The effects of the main parameters are analyzed resorting to a mathematical model, which is validated by a comparison with the experimental data. In particular it is demonstrated that an optimal value of the ratio of the rate of pervaporation to the rate of reaction maximizes the “intensification” of the process. Other benefits of the integrated process, such as the complete retention of the photocatalytic powder in the reacting solution and high degree of purification of the product are presented and discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-01-01 |