6533b858fe1ef96bd12b625e
RESEARCH PRODUCT
Thin Films by Multilayer Build-Up of Electron Transport Materials
Ralf MrukSabine PrehlRudolf Zentelsubject
Conductive polymerMaterials sciencePolymers and PlasticsOrganic ChemistryElectrochemistryElectron transport chainPolyelectrolyteCharacterization (materials science)chemistry.chemical_compoundchemistryChemical engineeringPolymer chemistryMaterials ChemistrySelf-assemblyThin filmTriazinedescription
We present the synthesis and the electrochemical characterization of polymeric electron transport materials, synthesized by polycondensation of substituted triazines and α,ω-dihaloalkanes. They can be reversibly reduced with the least negative potential at −0.39 V, which is below the reduction potential of oxygen. In addition, the formation of polyelectrolyte multilayers is possible by the electrostatic self-assembly method. This multilayer formation takes place in a very defined way up to thirty double layers. An example of one of the polymeric triazine electron transport materials synthesized and a schematic diagram of a self-assembled multilayer film.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-11-01 | Macromolecular Rapid Communications |