6533b858fe1ef96bd12b6bf9

RESEARCH PRODUCT

NLO Polymers Containing as Active Chromophore in Dandionylpyridinium, Betaine Units: Synthesis, Modeling and Characterization

O. DubrovichO. NeilandsInta MuzikanteVismants ZaulsMaris Utinans

subject

chemistry.chemical_classificationchemistry.chemical_compoundMaterials scienceBetainechemistryCovalent bondPolymer chemistryElectron donorPolymerChromophoreElectron acceptorOrganic compoundPolyurethane

description

In present article we report about synthesis, quantum chemical model calculations, non-linear optical characterization and dependencies of the surface potential changes on irradiation with light of novel polyurethane based polymers, namely a bipolar organic compound N-(indan-1,3-dion-2-y1)-4-N’,N’dialkylaminopyridinium betaine (IPB) containing charged electron donor and electron acceptor groups covalently bonded to polyurethane polymer backbone. These newly synthesized IPB containing polymers could be regarded as a promising thermally stable organic non-linear optical materials with long time performance for photonic applications.

https://doi.org/10.1007/978-94-011-4056-0_34