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RESEARCH PRODUCT

Mossbauer spectroscopic studies on the molecular dynamics of organotin(IV) polymers

Jan G. NoltesRenato BarbieriGiuseppe RuisiLorenzo PelleritoArturo Silvestri

subject

Lattice dynamicschemistry.chemical_classificationOrganic ChemistryInorganic chemistrychemistry.chemical_elementPolymerBiochemistryInorganic ChemistryMolecular dynamicschemistryMössbauer spectroscopyMaterials ChemistryPhysical chemistryPhysical and Theoretical ChemistryTin

description

Abstract Linear organotin(IV) polymers with tin appended to the polymer chain or inserted into the polymer backbone have been characterized by Mossbauer spectroscopy. The lattice dynamics of three representative examples of these classes, as well as of a cross-linked organotin(IV) polymer, have been investigated by temperature-dependent Mossbauer spectroscopy. It has been shown that parameters associated with polymers having low interchain interactions practically correspond to those of molecular, non-coupled, solids.

https://doi.org/10.1016/s0022-328x(00)86643-7