6533b859fe1ef96bd12b75dc
RESEARCH PRODUCT
Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects
Zheng YanBin FeiJian ZhouIl'ya A. Gural'skiyXin BaoVadim KsenofontovSergii I. ShylinSergii I. Shylinsubject
010405 organic chemistrySolvothermal synthesisSubstitution (logic)General Chemistry010402 general chemistryCondensed Matter PhysicsPhotochemistry01 natural sciences0104 chemical sciencesMetalCrystallographychemistry.chemical_compoundDegree of substitutionchemistrySpin crossovervisual_artDiaminevisual_art.visual_art_mediumCluster (physics)General Materials ScienceTetradentate liganddescription
A pentanuclear [CoII3CoIII2] cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed Fe–Co derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree of substitution.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 | CrystEngComm |