6533b859fe1ef96bd12b76ca
RESEARCH PRODUCT
Pyrogallarenes as alkali metal receptors: the role of cation-pi interactions in complexation.
Maija NissinenAntti ÅHmansubject
HydrogenPotassiumInorganic chemistryCation πMetals and Alloyschemistry.chemical_elementAromaticityGeneral ChemistryAlkali metalCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsRubidiumlaw.inventionchemistrylawCaesiumPolymer chemistryMaterials ChemistryCeramics and CompositesCrystallizationdescription
Crystallization studies of C-methyl pyrogallarene with potassium, rubidium and caesium bromides or chlorides resulted in a hydrogen bonded molecular cage in which the alkali metal cations are eta6 coordinated to aromatic rings via strong cation-pi interactions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-03-07 | Chemical communications (Cambridge, England) |