High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

6533b859fe1ef96bd12b837d

RESEARCH PRODUCT

High oxidation state aqueous organometallics. Formation and structure of an oxo-centred CpMoV trinuclear cation by chemical reduction of Cp2Mo2O5

Jenny Gun Ovadia Lev Funda Demirhan Funda Demirhan Rinaldo Poli Alexandre Modestov Philippe Richard

subject

chemistry.chemical_classification Aqueous solution 010405 organic chemistry Inorganic chemistry Salt (chemistry)chemistry.chemical_element General Chemistry Zinc 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Ion law.invention chemistry Oxidation state law [CHIM.CRIS]Chemical Sciences/Cristallography Chemical reduction [CHIM.COOR]Chemical Sciences/Coordination chemistry Crystallization

description

International audience; Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH–H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF3)3]+ and [Zn2(O2CCF3)6]2− ions after crystallisation from THF–Et2O.

year	journal	country	edition	language
2002-01-01	Journal of the Chemical Society, Dalton Transactions

https://doi.org/10.1039/b203583a

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