Skābekļa atomu saturošie imidazolija sāļi kondensācijas reakcijās

6533b85afe1ef96bd12b8fff

RESEARCH PRODUCT

Skābekļa atomu saturošie imidazolija sāļi kondensācijas reakcijās

Līga Gradovska

subject

KNĒVENĀGELA KONDENSĀCIJA POLIETILĒNGLIKOLA FUNKCIONALIZĒTIE JONU ŠĶIDRUMI POLYETHYLENE GLYCOL FUNCTIONALIZED IONIC LIQUIDS KNOEVENAGEL CONDENSATION GĀZU HROMATOGRĀFIJA Ķīmija

description

Skābekļa atomu saturošie imidazolija sāļi kondensācijas reakcijās. Gradovska L., darba vadītāji Dr.h.ķīm., prof. Zicmanis A., Dr.chem. Baķis E. Maģistra darbs, 59 lappuses, 31 attēls, 5 tabulas, 43 literatūras avoti, 1 pielikums. Latviešu valodā. Literatūras apskatā apkopota informācija par biežāk aprakstītajiem jonu šķidrumiem un polietilēnglikola funkcionalizētajem jonu šķidrumiem, to iegūšanu un izmantošanas iespējām organiskajā katalīzē. Eksperimentālajā daļā sintezēti polietilēnglikola, spirtu un alkilvirkņu funkcionalizētie imidazolija rindas jonu šķidrumi, kuri izmantoti kā katalizatori un reakcijas vide Knēvenāgela kondensācijā. Reakcijas konversija atkarībā no laika novērtēta, izmantojot gāzu hromatogrāfiju. Izmantojot 1H KMR spektroskopiju, aplūkotas jonu šķidrumu katjona un anjona ķīmiskās nobīdes bezšķīdinātāja apstākļos un izvērtētas katjona un anjona iespējamās mijiedarbības, kas var ietekmēt Knēvenāgela reakcijas norisi.

year	journal	country	edition	language
2021-01-01

https://dspace.lu.lv/dspace/handle/7/55153

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