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RESEARCH PRODUCT
Magnetic properties of hybrid molecular materials based on oxalato complexes
Carlos Giménez-saizCarlos J. Gómez-garcíaJosé M. Martínez-agudoEugenio CoronadoJosé Ramón Galán-mascarósEugenia Martínez-ferrerosubject
Inorganic Chemistrychemistry.chemical_classificationParamagnetismchemistry.chemical_compoundChemistryPolymer chemistryInorganic chemistryMaterials ChemistrySalt (chemistry)Physical and Theoretical ChemistryMolecular materialsBimetallic stripTetrathiafulvalenedescription
Abstract The use of [MIII(ox)3]3− (MIII=Ru, Rh) complexes as building blocks for hybrid molecular materials is highlighted with two different synthetic approaches. The first strategy is the combination of organic donors and [RuIII(ox)3]3− units, resulting in the radical salt of formula TTF3[Ru(ox)3]·0.5EtOH·4H2O (1) which shows coexistence of paramagnetism and semiconducting properties. The second approach is the synthesis of extended 2D bimetallic oxalato-bridged networks of general formula [FeCp2 *][MIIRh(ox)3] in which paramagnetic layers of decamethylferricinium cations are alternated with paramagnetic bimetallic layers.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-07-01 |