6533b85afe1ef96bd12ba0ca
RESEARCH PRODUCT
Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?
Kang QianJacob OvergaardEugenio CoronadoYi-quan ZhangYi-quan ZhangAlejandro Gaita-ariñoSong GaoJosé J. BaldovíShang-da JiangShang-da JiangBing-wu Wangsubject
DiffractionCrystallographyMagnetic anisotropyCondensed matter physicschemistryMagnetThermalDysprosiumAb initiochemistry.chemical_elementGeneral ChemistrySingle crystalMagnetic susceptibilitydescription
A dysprosium based single-ion magnet is synthesized and characterized by the angular dependence of the single-crystal magnetic susceptibility. Ab initio and effective electrostatic analyses are performed using the molecular structures determined from single crystal X-ray diffraction at 20 K, 100 K and 300 K. Contrary to the common assumption, the results reveal that the structural thermal effects that may affect the energy level scheme and magnetic anisotropy below 100 K are negligible.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-01-01 |