6533b85bfe1ef96bd12baaf8

RESEARCH PRODUCT

Crystal structure of bis(ethylenedithio)tetrathiafulvalenium μ2-acetato-bis[tribromidorhenate(III)] 1,1,2-trichloroethane hemisolvate

Vladimir A. StarodubA. V. ShtemenkoDenis M. ChudakAlexander A. GolichenkoIrina V. OmelchenkoBolesław BarszczAndrey V. Kravchenko

subject

crystal structureStereochemistrybis­(ethyl­enedi­thio)­tetra­thia­fulvaleneStackingThio-Crystal structurerhenium010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesResearch CommunicationsCrystalquadruple metal–metal bondbis(ethylenedithio)tetrathiafulvaleneGeneral Materials Scienceradical cation saltCrystallographybiologyHydrogen bondChemistryLigandGeneral ChemistryCondensed Matter Physicsbiology.organism_classification0104 chemical sciencesCrystallographyRadical ionQD901-999Tetra

description

The crystal structure of a binuclear mono­carboxyl­ato dirhenium(III) complex with a fulvalene derivative is reported. This compound represents a radical cation salt containing a cluster unit with rhenium–rhenium quadruple bond.

10.1107/s2056989016006058http://scripts.iucr.org/cgi-bin/paper?S2056989016006058