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RESEARCH PRODUCT
Heterogeneous Dinuclear Rhodium(II) Hydroformylation Catalysts—Performance Evaluation and Silsesquioxane-Based Chemical Modeling
John E. DaviesBrian F. G. JohnsonThomas MaschmeyerMathias NowotnyJohn Meurig ThomasPascual Lahuertasubject
ChemistryChemical process modelingchemistry.chemical_elementGeneral ChemistryGeneral MedicineHeterogeneous catalysisCatalysisSilsesquioxaneRhodiumCatalysischemistry.chemical_compoundPolymer chemistryOrganic chemistryAmorphous silicaMesoporous materialHydroformylationdescription
Supported, air stable, and reusable hydroformylation catalysts have been prepared by immobilizing dinuclear rhodium(II) complexes bearing ortho-metalated arylphosphane ligands on amorphous silica and mesoporous MCM-41 supports by phosphane tethers. The oligosilsesquioxane model complex of the catalytic site 1 has been prepared analogously and characterized by single-crystal X-ray diffraction analysis.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2001-03-02 | Angewandte Chemie |