6533b85bfe1ef96bd12bac6a

RESEARCH PRODUCT

Controlling the position of anions relative to a pentafluorophenyl groupw

Michael GieseArto ValkonenKatharina WiemerKari RissanenMarkus Albrecht

subject

CrystallographyPosition (vector)StereochemistryGroup (periodic table)ChemistryMaterials ChemistryChemieOne-StepGeneral ChemistryIdeal (ring theory)ta116CatalysisIon

description

The position of an anion above an electron-deficient arene can be controlled by the geometry of appended directing groups. Here a series of ammonium substituted pentafluorophenyl derivatives is investigated. The presented results are one step on the way to find the ideal structural features for an effective and superior receptor for anion–π studies.

10.1039/c2nj40089hhttps://doi.org/10.1039/c2nj40089h