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RESEARCH PRODUCT
The effect of low pressure on a high-spin—low-spin transition
H. KöppenHartmut SpieringE. MeissnerPhilipp Gütlichsubject
Condensed matter physicsChemistryLattice (order)Mössbauer spectroscopyAnalytical chemistrySpin transitionGeneral Physics and AstronomyPhysical and Theoretical Chemistrydescription
Abstract The effect of low pressure ( p = 150 bar) on the high-spin (HS)—low-spin (LS) transition in [Fe x Zn 1− x (2-pic) 3 ]Cl 2 · EtOH ( x = 0.5, 1.0) was measured by Mossbauer spectroscopy and the results compared with theory. The linear dependence of the volume of the lattice on the HS fraction, which is the basic assumption of the theory, was proven by temperature dependent X-ray measurements.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1983-02-01 | Chemical Physics Letters |