6533b85bfe1ef96bd12bb3ad

RESEARCH PRODUCT

Complexes of organometallic compounds. XXXVIII. Anion Exchange Studies on the Trimethyllead (IV) Thiocyanate aqueous complex system

N. Bertazzi

subject

Inorganic Chemistrychemistry.chemical_compoundAqueous solutionThiocyanatechemistryIon exchangeStability constants of complexesPhase (matter)Inorganic chemistryAqueous two-phase systemIon-exchange resinGroup 2 organometallic chemistry

description

The distribution of Me3PbIV between the anion exchange resin Dowex 1 X 8 and aqueous solutions of NaSCN and KSCN was investigated. In the aqueous phase, up to 3 M thiocyanate concentration, only the formation of the neutral species Me3PbNCS was detected and the related stability constant evaluated. Evidence of formation into the resin phase of the anionic Me3Pb(NCS) species was obtained.

https://doi.org/10.1002/zaac.19744100312