6533b85bfe1ef96bd12bb40c
RESEARCH PRODUCT
Ultrasonic and Volumetric Properties of 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate Ionic Liquid with 2-Propanol or Tetrahydrofuran at Several Temperatures
Francisco J. LlopisVicenta González-alfaroA. Vicent OrchillésAntoni Martínez-andreuErnesto Verchersubject
General Chemical EngineeringAnalytical chemistryGeneral ChemistryPropanolchemistry.chemical_compound1-ethyl-3-methylimidazoliumMolar volumechemistrySpeed of soundIonic liquidOrganic chemistryUltrasonic sensorTrifluoromethanesulfonateTetrahydrofurandescription
Densities and speeds of sound of 1-ethyl-3-methylimidazolium trifluoromethanesulfonate mixtures with 2-propanol and tetrahydrofuran (THF), as well as of the pure components, have been measured over the whole range of compositions at T = (278.15 to 328.15) K and P = (101 ± 2) kPa. From these experimental data, the excess molar volume, excess speed of sound, and excess isentropic compressibility have been calculated and fitted to an extended version of the Redlich–Kister equation, which takes into account the dependence on composition and temperature simultaneously. The Prigogine–Flory–Patterson theory has also been used to explain the behavior of these systems.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-08-23 | Journal of Chemical & Engineering Data |