6533b85bfe1ef96bd12bb51c
RESEARCH PRODUCT
Interaction of Zn(II) and Cd(II) with Large Polyazacycloalkanes in dmso/H2O (80:20 vol./vol.). A potentiometric Study.
Victor MarcelinoAntonio BianchiJuan FausAndrea BenciniEnrique García-españasubject
Inorganic ChemistrySolventHydrolysisAqueous solutionChemistryInorganic chemistryPotentiometric titrationMaterials ChemistryProtonationPhysical and Theoretical ChemistryChemical equilibriumMedicinal chemistryIondescription
Abstract A potentiometric study on the interaction at 25 °C and 0.15 mol dm −3 between large polyazacycloalkanes of the series [3 k ]aneN k and Zn(II) and Cd(II) ions in dmso:H 2 O (80:20 vol./vol.) is reported. The protonation behavior of the free macrocycles and coordination trends are compared with those previously observed in aqueous solution. The main features observed in the mixed solvent are: similar protonation behavior of the free polyamines, greater tendency to form binuclear and protonated complexes and a lower tendency to bear hydrolytic reactions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1990-06-01 |