6533b85bfe1ef96bd12bbdf1

RESEARCH PRODUCT

N-trifluoracetyl-nylon 66 als polymeres reagenz

Engelbert J. GünsterRolf C. Schulz

subject

chemistry.chemical_compoundNylon 66chemistryReagentPolymer chemistrytechnology industry and agricultureOrganic chemistrymacromolecular substancesTrifluoroacetic anhydrideSelectivity

description

N-Trifluoroacetyl-Nylon 66 (2) obtained by the reaction of Nylon 66 (1) with trifluoroacetic anhydride is very suitable as a polymeric reagent for the trifluoroacetylation of amines and alcohols. The advantages of 2 compared with low molecular trifluoroacetylating reagents are discussed. The selectivity against different substituted anilines and against structurally isomeric secondary amines was studied intensively by kinetic measurements.

https://doi.org/10.1002/macp.1979.021800804