6533b85cfe1ef96bd12bd1a7

RESEARCH PRODUCT

A kinetic-catalytic method for iodide based on the simultaneous addition of inhibitor and substrate

V.pineda SalesG.ramis RamosM.c.garcía Alvarez-coqueR. M. Villanueva Camañas

subject

Absorbancechemistry.chemical_classificationChemistryInorganic chemistryIodideSubstrate (chemistry)Reaction inhibitorKinetic energyChemical reactionSpectroscopyCatalytic methodAnalytical ChemistryCatalysis

description

Abstract A kinetic-catalytic method of analysis, based on the addition of a mixture of inhibitor and substrate, at a constant rate, over the catalyst in the presence of the other component of the indicator reaction is studied. The method is applied to the determination of iodide using the Ce(IV)As(III) catalytic reaction and Hg(II) as inhibitor. Under suitable experimental conditions the absorbance of the unconsumed Ce(IV) is inversely proportional to the initial iodide concentration.

https://doi.org/10.1016/0026-265x(87)90157-3