6533b85cfe1ef96bd12bd3e4
RESEARCH PRODUCT
cis,cis,cis-(Acetato-k2O,O´)bis[1,2-bis- (diphenylphosphanyl)ethane-k2P,P´]- ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride
Arto ValkonenJoão FigueiraJoão Rodriguessubject
Metal-Organic PapersLigandchemistry.chemical_elementMethane sulfonateGeneral Chemistry010402 general chemistry010403 inorganic & nuclear chemistryCondensed Matter Physics01 natural sciencesMedicinal chemistryChloride3. Good health0104 chemical sciencesRutheniumchemistrymedicineGeneral Materials Scienceta116medicine.drugdescription
In the title Ru(II) carboxyl-ate compound, [Ru(C2H3O2)(C26H24P2)2](CF3O3S)0.75Cl0.25, the distorted tris-bidentate octa-hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis-(diphenyl-phosphan-yl)ethane ligands [Ru-P = 2.2881 (13)-2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoro-methane-sulfonate anions and one chloride anion, with two such formula units in the unit cell.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-03-23 | Acta Crystallographica Section E: Structure Reports Online |