6533b85cfe1ef96bd12bd511
RESEARCH PRODUCT
Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions.
Eugenia Miguel-casañMohanad D. DarawshehVíctor Fariña-torresIñigo J. Vitórica-yrezábalEduardo Andres-garciaMartín Fañanás-mastralGuillermo Mínguez Espallargassubject
General ChemistryMetalls de transicióReaccions químiquesdescription
Palladium-based metal-organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(II) was successfully incorporated in the framework of a MOF denoted as MUV-22 using a solvent assisted reaction. This stable MOF, with square-octahedron (soc) topology as MIL-127, and a porosity of 710 m2 g−1, is highly active, selective, and recyclable for the Suzuki-Miyaura allylation of aryl and alkyl boronates as exemplified with the coupling between cinnamyl bromide and Me-Bpin, a typically reluctant reagent in cross-coupling reactions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2022-09-18 | Chemical science |