6533b85dfe1ef96bd12bdcc0

RESEARCH PRODUCT

Tris(2-thienyl)methyl cation; An unprecedent 13C NMR behavior

Belén AbarcaCarmen LunaGregorio AsensiosRafael Ballesteros

subject

Trischemistry.chemical_compoundStereochemistryChemistryOrganic ChemistryDrug DiscoveryChemical solutionNuclear magnetic resonance spectroscopyCarbon-13 NMRCarbocationBiochemistryMedicinal chemistry

description

Abstract An unexpected response of the chemical shift value to the substitution of phenyl by thienyl groups is found in the series 1–8 . On this basis the planar cation 7 appears to show an homoaromatic-like peripheral ring current.

https://doi.org/10.1016/s0040-4039(00)85293-4