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RESEARCH PRODUCT
Synthesis of P-Chirogenic Diphosphinotriazoles and Their Use in Asymmetric Catalysis
Raluca Malacea-kabbaraYoann RousselinJérôme Bayardonsubject
010405 organic chemistryChemistryEnantioselective synthesischemistry.chemical_element[CHIM]Chemical SciencesGeneral Chemistry010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical sciencesPalladiumdescription
International audience; The stereoselective synthesis of P-chirogenic diphosphinotriazoles using ephedrine methodology was described. The coordination behavior of these compounds as P,P-ligands has been demonstrated by the preparation as well as the spectroscopic and X-ray crystallographic analyses of a palladium complex. The efficiency of these new P-chirogenic diphosphines in the palladiumcatalyzed asymmetric allylic substitution reaction was also evaluated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-03-17 |