6533b85dfe1ef96bd12be5a7
RESEARCH PRODUCT
Polyoxometalate salts of cationic nitronyl nitroxide free radicals
Francisco M. RomeroCarlos J. Gómez-garcíaCarlos Giménez-saizEugenio Coronadosubject
Nitroxide mediated radical polymerizationChemistryMagnetismRadicalCationic polymerizationGeneral ChemistryCondensed Matter PhysicsPhotochemistrychemistry.chemical_compoundMetallatePolyoxometalatePolymer chemistryDimethylformamideGeneral Materials ScienceGroup 2 organometallic chemistrydescription
The cationic nitronyl nitroxide free radical of the N-methylpyridinium type p-MepyNN + has been combined with [Mo 8 0 26 ] 4- and Keggin [SiW 12 0 40 ] 4- polyanions to afford salts ( p-MepyNN) 4 [Mo 8 0 26 ] DMSO (DMSO = dimethylsulfoxide) (1) and (p-MepyNN)4[SiW 12 0 40 ] 6DMF (DMF = dimethylformamide) (2). Herein, their structural and magnetic properties are described.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-12-01 | Solid State Sciences |