Metamagnetic behaviour in a new Cu(ii)Re(iv) chain based on the hexachlororhenate(iv) anion

6533b85dfe1ef96bd12be843

RESEARCH PRODUCT

Metamagnetic behaviour in a new Cu(ii)Re(iv) chain based on the hexachlororhenate(iv) anion

Wdeson P. Barros José Martínez-lillo John Kong Juan Faus Miguel Julve Euan K. Brechin

subject

Chemistry Stereochemistry Metals and Alloys General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion Metal Crystallography Paramagnetism Chain (algebraic topology)visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium

description

A new chloro-bridged heterobimetallic Cu(ii)Re(iv) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (·MeCN) has been prepared and magnetostructurally characterised. Compound is the first example of the [Re(IV)Cl6](2-) anion acting as a metalloligand towards a paramagnetic metal ion.

year	journal	country	edition	language
2014-04-25	Chemical Communications

https://doi.org/10.1039/c4cc01564a

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