Isobaric Vapor−Liquid Equilibria for Binary and Ternary Mixtures of Ethanol, Methylcyclohexane, and p-Xylene

6533b85dfe1ef96bd12bf0bb

RESEARCH PRODUCT

Isobaric Vapor−Liquid Equilibria for Binary and Ternary Mixtures of Ethanol, Methylcyclohexane, and p-Xylene

† María Del Carmen Sánchez-russinyol And Antonio Aucejo Sonia Loras

subject

chemistry.chemical_compound UNIQUAC Ternary numeral system chemistry General Chemical Engineering Azeotrope Isobar Non-random two-liquid model Isobaric process Thermodynamics General Chemistry Methylcyclohexane Ternary operation

description

Consistent vapor−liquid equilibria (VLE) were determined for the ternary system ethanol + methylcyclohexane + p-xylene and the three binary subsystems at 101.3 kPa at temperatures in the range from 345 to 408 K. The binary systems exhibit positive deviation from ideal behavior, and the system ethanol + methylcyclohexane presents a minimum-boiling-point azeotrope. The VLE data have been correlated by the Wilson, NRTL, and UNIQUAC equations. The ternary system does not present an azeotrope and is well predicted from binary interaction parameters.

year	journal	country	edition	language
2004-07-16	Journal of Chemical & Engineering Data

https://doi.org/10.1021/je0342318

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