6533b85dfe1ef96bd12bf1de
RESEARCH PRODUCT
Reductive cleavage of 2,2,2-trichloroethyl esters with sodium telluride
C. L. GarciaBegoña GarcíaLuz CardonaGonzalo BlayJosé R. Pedrosubject
Reaction conditionschemistry.chemical_compoundChemistryReductive cleavageOrganic ChemistrySodium tellurideOrganic chemistryDimethylformamidedescription
Abstract Carboxylic acids are regenerated from their 2,2,2-trichloroethyl esters by treatment with sodium telluride in dimethylformamide in smooth conditions and with good yields. The reaction conditions are compatible with other functional and protective groups such as methyl ester, acetate or tert-butyldimethylsilyl ethers.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1998-04-01 |