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RESEARCH PRODUCT
Filling the Gap in the Metallacrown Family: The 9‐MC‐3 Chromium Metallacrown
Anne LüpkeEva RentschlerLuca M. Carrellasubject
9-MC-3540 Chemistry and allied sciencesCluster Compounds | Hot PaperCommunicationOrganic Chemistrykinetic stabilityStructural integritychemistry.chemical_elementGeneral ChemistrySolvothermal reactionCatalysisCommunicationsIonmetallacrownMagnetizationCrystallographyChromiumchemistry.chemical_compoundstructural integritychemistry540 ChemieMorpholinechromiumGround stateMetallacrowndescription
Abstract In this work, we report on a long‐sought missing complex in the metallacrown family. We synthesized and characterized the novel chromium metallacrown (MC) complex {CrIII(μ 2‐piv)3[9‐MCCr(III)N(shi)‐3](morph)3}⋅MeOH (in which shi3−=salicyl hydroxamate, piv=pivalate, and morph=morpholine). The MC with a 9‐MC‐3 cavity of kinetically inert chromium(III) ions was synthesized by a solvothermal reaction. Magnetization measurements reveal a high spin ground state.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-03-01 | Chemistry (Weinheim an Der Bergstrasse, Germany) |