Communication: Evidence of structural phase transitions in silicalite-1 by infrared spectroscopy

6533b85efe1ef96bd12bf44f

RESEARCH PRODUCT

Communication: Evidence of structural phase transitions in silicalite-1 by infrared spectroscopy

Maud Rotger Jean-pierre Bellat Anthony Ballandras Guy Weber Christian Paulin

subject

In situ Structural phase Adsorption Chemistry Molecular vibration Analytical chemistry General Physics and Astronomy Infrared spectroscopy Physical and Theoretical Chemistry Fourier transform infrared spectroscopy Zeolite Spectral line

description

The adsorption of trichloroethylene, perchloroethylene, and p-xylene on a MFI (Mobile-FIve) zeolite is studied using in situ FTIR spectroscopy at 298 K. Spectra of self-supported zeolites in contact with increasing pressures of pure gas were recorded at equilibrium in the mid-infrared domain. Analysis of the evolution of the shape and location of vibrational bands of the zeolite as a function of the amount adsorbed allowed the observation of structural modifications of the adsorbent for the first time by infrared spectroscopy.

year	journal	country	edition	language
2013-09-07	The Journal of Chemical Physics

https://doi.org/10.1063/1.4819080

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